Numéro |
J. Phys. I France
Volume 3, Numéro 10, October 1993
|
|
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Page(s) | 1987 - 1991 | |
DOI | https://doi.org/10.1051/jp1:1993226 |
DOI: 10.1051/jp1:1993226
J. Phys. I France 3 (1993) 1987-1991
1 Institute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznan, Poland
2 Department of Chemisty, University of Warszawa, 02-093 Warszawa, Poland
© Les Editions de Physique 1993
J. Phys. I France 3 (1993) 1987-1991
New sulfur-fullerite; its preparation, structure and spectral properties
N.D. Kushch1, I. Majchrzak1, W. Ciesielski1, A. Graja1, K. Wozniak2 and T.M. Krygowski21 Institute of Molecular Physics, Polish Academy of Sciences, 60-179 Poznan, Poland
2 Department of Chemisty, University of Warszawa, 02-093 Warszawa, Poland
(Received 8 July 1993, accepted in final form 3 August 1993)
Abstract
The preparation and unit cell parameters of a novel fullerene-containing compound, (C
60)
6S
C
2HCl
3, is described. The compound is orthorhombic with
a = 10.512(6) Å,
b = 21.072(26) Å and
c = 38.985(50) Å. The UV-VIS-NIR-IR spectra of the compound are analysed. It is concluded that the new sulfur-fullerite is true van der
Walls solid without strong interactions between the constituent molecules.
© Les Editions de Physique 1993