J. Phys. I France
Volume 6, Numéro 4, April 1996
Page(s) 503 - 527
DOI: 10.1051/jp1:1996227
J. Phys. I France 6 (1996) 503-527

Residual-Impurity Effects in Directional Solidification: Long-Lasting Recoil of the Front and Nucleation-Growth of Gas Bubbles

Silvère Akamatsu and Gabriel Faivre

Groupe de Physique des Solides CNRS URA 17, Universités Denis-Diderot et Pierre- et Marie-Curie, Tour 23, 2 place Jussieu, 75251 Paris Cedex 05, France

(Received 22 September 1995, received in final form 26 December 1995, accepted 4 January 1996)

Directional-solidification experiments are often perturbed by the nucleation of gas bubbles and other residual-impurity effects. We present a detailed experimental study of these phenomena in the system CBr 4-C 2Cl 6 directionally solidified in thin films. As is usual in this type of experiments, we use zone-refined and outgased products, but do not fill and seal the samples under vacuum. We study the solute-redistribution transient (initial recoil of the growth front) in samples of as-refined CBr 4, in the absence of bubbles. This in situ method allows us to detect all the impurities present in our samples and to estimate their concentrations and partition coefficients. We point out several artefacts that may be caused by the dissolved residual impurities (shift of the cellular threshold velocity, modifications of the morphology of the cellular front). We then describe in detail the nucleation-growth process of gas bubbles during the course of solidification. There exists a steady growth pattern consisting of a periodic array of tubular bubbles similar to the rod-like pattern of eutectics and monotectics. We study the morphology of this state as a function of the growth velocity. We show that, at high velocity, the pattern decomposes in a series of independent local two-phased structures, the solid-vapour (SV) fingers, of width a few diffusion lengths. Between the SV fingers, the front is unperturbed.

© Les Editions de Physique 1996